1025363-85-2

Basic information

• Product Name: [N{20P(CHMe₂)2-4-MeC₆H₃}2]Ir(CO)
• Synonyms: [N{20P(CHMe₂)2-4-MeC₆H₃}2]Ir(CO)
• CAS NO: 1025363-85-2
• Molecular Weight: 648.788
• Mol File: 1025363-85-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [N{20P(CHMe₂)2-4-MeC₆H₃}2]Ir(CO)(CAS DataBase Reference)
• NIST Chemistry Reference: [N{20P(CHMe₂)2-4-MeC₆H₃}2]Ir(CO)(1025363-85-2)
• EPA Substance Registry System: [N{20P(CHMe₂)2-4-MeC₆H₃}2]Ir(CO)(1025363-85-2)

Safety Data

• Hazardous Substances Data: 1025363-85-2(Hazardous Substances Data)

Upstream product

• 925-93-9 ethyl [2]alcohol 
• 1086717-30-7 [N{20P(CHMe₂)2-4-MeC₆H₃}2]Ir(N₂) 

Relevant articles and documents

Decarbonylation of ethanol to methane, carbon monoxide and hydrogen by a [PNP]Ir complex

The putative three-coordinate Ir(i) PNPPri(PNPPri = [N{2-P(CHMe2)2-4-MeC6H3} 2]-) pincer complex decarbonylates ethanol to yield methane, hydrogen and [PNPPri]Ir(CO). The mechanism involves the isolable trans-[PNPPri]Ir(H)(Me)(CO), which is susceptible to photochemical reductive elimination of methane.