102548-26-5

Basic information

• Product Name: Pyridine,2-[(2-propenyloxy)methyl]-(9CI)
• Synonyms: Pyridine,2-[(2-propenyloxy)methyl]-(9CI);2-(allyloxymethyl)pyridine
• CAS NO: 102548-26-5
• Molecular Formula: C₉H₁₁NO
• Molecular Weight: 149.18974
• Product Categories: PYRIDINE
• Mol File: 102548-26-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Pyridine,2-[(2-propenyloxy)methyl]-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine,2-[(2-propenyloxy)methyl]-(9CI)(102548-26-5)
• EPA Substance Registry System: Pyridine,2-[(2-propenyloxy)methyl]-(9CI)(102548-26-5)

Safety Data

• Hazardous Substances Data: 102548-26-5(Hazardous Substances Data)

Upstream product

• 4377-33-7 2-chloromethylpyridine 
• 20907-32-8 sodium allyloxide 
• 107-18-6 allyl alcohol 

Downstream Products

• 17285-57-3 1-(2-pyridinyl)but-3-en-1-ol 
• 22971-32-0 1-(pyridin-2-yl)butan-1-one 
• 109-06-8 α-picoline 

Relevant articles and documents

Stereoselective and competitive [1,2]- and [2,3]-wittig rearrangements of allyl heteroarylalkyl ethers

Several allyl heteroarylalkyl ethers have been synthesized and then deprotonated with nBuLi in THF at -78°C to give lithium derivatives. The lithium-bearing terminus was either the α- or the α′-carbon atom, depending on the associated proton acidity. In the absence of an external electrophile, a sigmatropic rearrangement occurs, generating a new C-C bond. Heteroarylalkyl homoallylic alcohols and allyl heteroarylalkylic alcohols were obtained as products of stereoselective [2,3]- or [1,2]-Wittig rearrangements, respectively. Homoallylic alcohols were obtained in high yields and with fairly good enantiomeric enrichments when the reactions were carried out in toluene with (-)-sparteine as the external chiral ligand.