1025505-77-4

Basic information

• Product Name: (S)-4-phenyl-[1,2,3]-oxathiazolidine 2,2-dioxide
• Synonyms: (S)-4-phenyl-[1,2,3]-oxathiazolidine 2,2-dioxide
• CAS NO: 1025505-77-4
• Molecular Weight: 199.23
• Mol File: 1025505-77-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (S)-4-phenyl-[1,2,3]-oxathiazolidine 2,2-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-phenyl-[1,2,3]-oxathiazolidine 2,2-dioxide(1025505-77-4)
• EPA Substance Registry System: (S)-4-phenyl-[1,2,3]-oxathiazolidine 2,2-dioxide(1025505-77-4)

Safety Data

• Hazardous Substances Data: 1025505-77-4(Hazardous Substances Data)

Upstream product

• 106881-52-1 benzeneethanol sulfamate (ester) 
• 1025506-03-9 4-phenyl-5H-[1,2,3]-oxathiazole-2,2-dioxide 
• 582-24-1 1-phenyl-2-hydroxyethanone 

Downstream Products

• 20989-17-7 (2S)-2-phenylglycinol 
• 930598-65-5 (S)-3-Benzyl-4-phenyl-[1,2,3]-oxathiazolidine-2,2-dioxide 

Relevant articles and documents

Enantioselective Access to Chiral Cyclic Sulfamidates Through Iridium-Catalyzed Asymmetric Hydrogenation

The Iridium-catalyzed asymmetric hydrogenation of cyclic sulfamidate imines was successfully developed with N-methylated ZhaoPhos L2 as the ligand. A variety of chiral cyclic sulfamidates were obtained with excellent results (up to 99% yield, 99% ee). Furthermore, this asymmetric hydrogenation can be employed as the key reaction step to prepare the important intermediates in organic synthesis. (Figure presented.).

Enantioselective synthesis of cyclic sulfamidates via Pd-catalyzed hydrogenation

Using Pd(CF3;CO2)2/(S,S)-f-binaphane as the catalyst, an efficient enantioselective synthesis of cyclic sulfamidates was developed via asymmetric hydrogenation of the corresponding cyclic imines in 2,2,2-trifluoroethanol at room temperature with high enantioselectivities (up to 99% ee).