1025510-63-7

Basic information

• Product Name: 1-bromo-2-(2-trimethylsilylethoxymethoxy)-4-(2-trimethylsilylethoxymethoxymethyl)benzene
• Synonyms: 1-bromo-2-(2-trimethylsilylethoxymethoxy)-4-(2-trimethylsilylethoxymethoxymethyl)benzene
• CAS NO: 1025510-63-7
• Molecular Weight: 463.559
• Mol File: 1025510-63-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-bromo-2-(2-trimethylsilylethoxymethoxy)-4-(2-trimethylsilylethoxymethoxymethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bromo-2-(2-trimethylsilylethoxymethoxy)-4-(2-trimethylsilylethoxymethoxymethyl)benzene(1025510-63-7)
• EPA Substance Registry System: 1-bromo-2-(2-trimethylsilylethoxymethoxy)-4-(2-trimethylsilylethoxymethoxymethyl)benzene(1025510-63-7)

Safety Data

• Hazardous Substances Data: 1025510-63-7(Hazardous Substances Data)

Upstream product

• 2737-19-1 4-bromo-3-hydroxy-benzyl alcohol 
• 76513-69-4 (2-trimethylethylsilylethoxy)methyl chloride 

Relevant articles and documents

Asymmetric total synthesis of (+)-curcutetraol and (+)-sydonol

The asymmetric total syntheses of (+)-curcutetraol and (+)-sydonol, phenolic bisabolane-type sesquiterpenoids having chiral tertiary alcohol moiety in the o-position of a phenol, were achieved in high enantiomeric excesses (99% ee). The chiral tertiary benzylic alcohol moiety of these compounds was constructed by an asymmetric synthesis using an easily available chiral aminal, (-)-(2R,5S)-2-methoxycarbonyl-3-phenyl-1,3-diazabicyclo[3.3.0]octane. The absolute configurations of both (+)-curcutetraol and?(+)-sydonol have been assumed to be S-configuration based on the stereochemical course of the well established asymmetric synthesis used in the syntheses.