10258-65-8Relevant academic research and scientific papers
Reactions of arenediazonium tetrafluoroborates with inorganic and organic salts
Grishchuk,Gorbovoi,Zagrichuk,Ganushchak,Kudrik
, p. 1299 - 1303 (2007/10/03)
Arenediazonium tetrafluoroborates were reacted with inorganic and organic salts under anionarylation reaction conditions in the presence of strong nucleophiles (O,O-dimetyl dithiophosphate, N,N-diethyldithiocarbamate, and O-alkyl dithiocarbonate anions) and in the absence of catalysts [Cu(I) and Fe(II) salts] to obtain in high yields (dimethoxythiophosphinoylmercapto)-, (N,N-diethylthiocarbamoylmercapto)-, and (alkoxythiocarbonylmercapto)benzenes. The products of the reactions of arenediazonium tetrafluoroborates with potassium thiocyanate were identified and their compositions were determined. These reactions are proposed to occur by a radical mechanism, both under catalytic and noncatalytic conditions.
Dimethylphosphinothioylthioarylation of Vinyl Butyl Ether
Grishchuk,Kudrik,Gorbovoi,Ganushchak,Avrashkova
, p. 1556 - 1558 (2007/10/03)
On the basis of anionarylation reaction a method for preparing dithiophosphoric acid derivatives, 1-butoxy-2-arylethyl O,O-dimethyl phosphorodithioates was developed. The reaction of aryldiazonium tetra-fluoroborates with vinyl butyl ether in the presence of O,O-dimethyl phosphorodithioate anion is a new example of a noncatalyzed reaction of diazonium salts with alkenes in the presence of foreign nucleophiles. A mechanism of such reactions is proposed.
