102614-79-9Relevant academic research and scientific papers
ETUDE CINETIQUE DE L'OUVERTURE THERMIQUE DE LA LIAISON C-C D'AZIRIDINES, YLURES D'AZOMETHINE POTENTIELS. III. EFFETS DE SOLVANT
Derdour, Aicha,Blaise, Paul,Texier, Fernand
, p. 721 - 726 (2007/10/02)
Kinetics of the thermal ring opening of 2-cyano aziridines and of one 2-aroyl aziridine carried out in different solvents showed that the solvent effect is very weak.Statistical treatement of kinetics distinguished the benzenic solvents from others.A specific solvatation of aziridine in benzenic solvents is found and the decimal logarithm of the rate constant k1 may be correlated with the Hammett ?*p values.These results may be interpreted in terms of interaction between the ? molecular orbital of benzene and the ?*C-C one of aziridine.
