102618-91-7

Basic information

• Product Name: 2H-1,3,5-Oxadiazine-2,4(3H)-dione, 6-(1,1-dimethylethyl)-
• Synonyms: 2H-1,3,5-Oxadiazine-2,4(3H)-dione, 6-(1,1-dimethylethyl)-
• CAS NO: 102618-91-7
• Molecular Formula: C₇H₁₀N₂O₃
• Molecular Weight: 0
• Mol File: 102618-91-7.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2H-1,3,5-Oxadiazine-2,4(3H)-dione, 6-(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-1,3,5-Oxadiazine-2,4(3H)-dione, 6-(1,1-dimethylethyl)-(102618-91-7)
• EPA Substance Registry System: 2H-1,3,5-Oxadiazine-2,4(3H)-dione, 6-(1,1-dimethylethyl)-(102618-91-7)

Safety Data

• Hazardous Substances Data: 102618-91-7(Hazardous Substances Data)

Upstream product

• 75-98-9 Trimethylacetic acid 
• 6498-10-8 carbonyl diisocyanate 
• 102618-89-3 3-Pivaloyl-2H-1,3,5-oxadiazine-2,4,6(3H,5H)-trione 

Downstream Products

• 58850-86-5 1-Pivaloylurea 

Relevant articles and documents

Reactions of Carbonyl Diisocyanate with Amides and Acids

Carbonyl diisocyanate (1) reacts with primary amides to give 1-acylated isocyanuric acids (5, 6).With secondary amides, 1 affords the rather instable oxadiazinediones 4, which for certain substituents rearrange to give triazines (5, 10).With nucleophiles, compounds 4 give oligourets, e.g. with ureas pentaurets (11, 12) were obtained.Carbonyl diisocyanate reacts with hydrogen halides to afford the crystalline urea-1,3-dicarbonyl halides 13a-c.Diverse products (16, 17, 24, 26) were obtained with carboxylic acids.In most cases oxadiazinediones (26) were isolated, which can be transformed with nucleophiles into acyl ureas 30, 31, biurets 32, and triurets 33.Acetylation of 26 leads to the reactive heterocycles 34.