102619-06-7

Basic information

• Product Name: [1-(4-methylphenylsulfonyl)pyrrol-2-yl]methanol
• Synonyms: [1-(4-methylphenylsulfonyl)pyrrol-2-yl]methanol
• CAS NO: 102619-06-7
• Molecular Weight: 251.306
• Mol File: 102619-06-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: [1-(4-methylphenylsulfonyl)pyrrol-2-yl]methanol(CAS DataBase Reference)
• NIST Chemistry Reference: [1-(4-methylphenylsulfonyl)pyrrol-2-yl]methanol(102619-06-7)
• EPA Substance Registry System: [1-(4-methylphenylsulfonyl)pyrrol-2-yl]methanol(102619-06-7)

Safety Data

• Hazardous Substances Data: 102619-06-7(Hazardous Substances Data)

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 17639-64-4 N-p-toluenesulfonylpyrrole 
• 216171-18-5 2-chloromethyl-1-methanesulfonyl-1H-pyrrole 
• 202580-86-7 (1-methanesulfonyl-1H-pyrrol-2-yl)methanol 
• 123892-38-6 1-(methylsulfonyl)-1H-pyrrole-2-carbaldehyde 
• 1003-29-8 2-pyrrole aldehyde 
• 102619-05-6 1-(toluene-4-sulfonyl)-1H-pyrrole-2-carbaldehyde 

Downstream Products

• 102619-07-8 1-(4-Methylphenylsulfonyl)-2-<(2-propinyloxy)methyl>pyrrol 
• 1188297-06-4 N-[4-(4-methoxyphenoxy)-2-methylbut-3-yn-2-yl]-4-methyl-N-[(1-tosyl-1H-pyrrol-2-yl)methyl]benzenesulfonamide 

Relevant articles and documents

Pd-catalyzed allylative dearomatisation using Grignard reagents

Pd-catalyzed allylative dearomatisation of naphthyl halides is shown to be feasible by employing Grignard reagents. The high reactivity of the nucleophile allows for fast reactions and low catalyst loading, while a plethora of successfully substituted compounds illustrate the broad scope. Five membered heteroaromatic compounds are also demonstrated to be reactive under similar conditions.

Rh(II)-Catalyzed Monocyclopropanation of Pyrroles and Its Application to the Synthesis Pharmaceutically Relevant Compounds

Here we report Rh(II)-catalyzed monocyclopropanation reactions on pyrroles in the presence of aryldiazoacetates, providing the corresponding dearomatized products with high levels of enantioselectivity (up to >99% ee). Under the catalysis of Rh2/sub

Palladium-catalyzed regioselective allylation of five-membered heteroarenes with allyltributylstannane

Palladium-catalyzed allylation reactions of 2-(chloromethyl)thiophenes, 2-(chloromethyl)furans, and N-protected 2-(chloromethyl)-1H-pyrroles with allyltributylstannane were described in this study. This type of allylation reaction regioselectively occurred on the heteroarene rings to produce allylated dearomatization products or allylated heteroarenes with satisfactory yields.