10264-19-4Relevant academic research and scientific papers
Volatiles from the Psychrotolerant Bacterium Chryseobacterium polytrichastri
Lauterbach, Lukas,Dickschat, Jeroen S.
, p. 3608 - 3617 (2020/09/22)
The flavobacterium Chryseobacterium polytrichastri was investigated for its volatile profile by use of a closed-loop stripping apparatus (CLSA) and subsequent GC-MS analysis. The analyses revealed a rich headspace extract with 71 identified compounds. Compound identification was based on a comparison to library mass spectra for known compounds and on a synthesis of authentic standards for unknowns. Important classes were phenylethyl amides and a series of corresponding imines and pyrroles.
Direct synthesis of imines from alcohols and amines with liberation of H2
Gnanaprakasam, Boopathy,Zhang, Jing,Milstein, David
supporting information; experimental part, p. 1468 - 1471 (2010/05/02)
"Chemical equation presented" A clean sweep: Aryl and aliphatic mines can be synthesized directly and efficiently from alcohols and amines under mild, neutral conditions with the liberation of only molecular hydrogen and water (see scheme; R=isopropyl, tert-butyl). This general, environmentally benign reaction is catalyzed by a de-aromatized ruthenium PNP pincer complex (0.2 mol%), and can proceed in toluene under an inert atmosphere or under air.
