102653-38-3Relevant academic research and scientific papers
2-Pyridonate titanium complexes for chemoselectivity. accessing intramolecular hydroaminoalkylation over hydroamination
Chong, Eugene,Schafer, Laurel L.
supporting information, p. 6002 - 6005 (2014/01/06)
Chemoselectivity of intramolecular hydroaminoalkylation over hydroamination has been achieved with a bis(3-phenyl-2-pyridonate) titanium complex. Primary aminoalkenes are selectively α-alkylated by C-H functionalization adjacent to nitrogen to access five
Titanium-catalyzed hydroaminoalkylation of alkenes by C-H bond activation at sp3 centers in the α-position to a nitrogen atom
Kubiak, Raphael,Prochnow, Insa,Doye, Sven
supporting information; experimental part, p. 1153 - 1156 (2009/06/19)
(Chemical Equation Presented) Good for primary and secondary amines: Hydroaminoalkylations of alkenes, which take place by C-H bond activation in the α-position to nitrogen atoms, are catalyzed by various neutral titanium complexes (see scheme). Primary a
