1026729-40-7Relevant academic research and scientific papers
Efficient palladium-catalyzed coupling of Baylis-Hillman acetates with an allylstannane
Park, Jinhyung,Kwon, Young Bum,Yang, Kyungmo,Rhee, Hakjune,Yoon, Cheol Min
experimental part, p. 661 - 665 (2010/04/26)
Acetates of Baylis-Hillman adducts derived from ethyl acrylate, methyl vinyl ketone, and acrylonitrile were coupled with allyltributylstannane using Pd(PPhor Pd(dba)as the catalyst at room temperature to afford the corresponding trisubstituted alka-1,5-di
Boron trifluoride-diethyl etherate complex mediated allylation of Baylis-Hillman adducts: A facile synthesis of 1,5-dienes
Yadav, Jhillu S.,Reddy, Basi V. Subba,Mandal, Satadru S.,Singh, Ashutosh Pratap,Basak, Ashok K.
experimental part, p. 1943 - 1947 (2009/04/04)
Morita-Baylis-Hillman adducts undergo smooth allylic nucleophilic substitution (SN2′) with allyltrimethylsilane in the presence of BF3·OEt2 under mild reaction conditions to afford 1,5-diene derivatives in good yields with high selectivity.
