1026773-66-9

Basic information

• Product Name: (2R,3R,αR,α'R,E)-methyl 3-(N-benzyl-N-α-methylbenzylamino)-2-[(N-benzyl-N-α-methylbenzylamino)-methyl]-5-phenyl-pent-4-enoate
• Synonyms: (2R,3R,αR,α'R,E)-methyl 3-(N-benzyl-N-α-methylbenzylamino)-2-[(N-benzyl-N-α-methylbenzylamino)-methyl]-5-phenyl-pent-4-enoate
• CAS NO: 1026773-66-9
• Molecular Weight: 622.85
• Mol File: 1026773-66-9.mol

Chemical Properties

• CAS DataBase Reference: (2R,3R,αR,α'R,E)-methyl 3-(N-benzyl-N-α-methylbenzylamino)-2-[(N-benzyl-N-α-methylbenzylamino)-methyl]-5-phenyl-pent-4-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,αR,α'R,E)-methyl 3-(N-benzyl-N-α-methylbenzylamino)-2-[(N-benzyl-N-α-methylbenzylamino)-methyl]-5-phenyl-pent-4-enoate(1026773-66-9)
• EPA Substance Registry System: (2R,3R,αR,α'R,E)-methyl 3-(N-benzyl-N-α-methylbenzylamino)-2-[(N-benzyl-N-α-methylbenzylamino)-methyl]-5-phenyl-pent-4-enoate(1026773-66-9)

Safety Data

• Hazardous Substances Data: 1026773-66-9(Hazardous Substances Data)

Upstream product

• 124957-40-0 (E)-methyl 3-acetoxy-2-methylene-5-phenyl-pent-4-enoate 
• 124575-69-5 methyl (4E)-3-hydroxy-2-methylene-5-phenylpent-4-enoate 
• 38235-77-7 (R)-N-benzyl-1-phenylethylamine 
• 124957-46-6 (2E,4E)-methyl 2-acetoxymethyl-5-phenyl-penta-2,4-dienoate 

Relevant articles and documents

Enantioselective synthesis of cis-(2S,3R)- and trans-(2S,3S)- piperidinedicarboxylic acids using domino: Allylic acetate and Ireland-Claisen rearrangements and Michael addition as the key steps

An enantioselective synthesis of (2S,3R)-piperidine-2,3-dicarboxylic acid and (2S,3S)-piperidine-2,3-dicarboxylic acid is described. This synthesis was mainly based on a δ-amino acid formation via a domino reaction: allylic acetate rearrangement, stereose