1027054-89-2Relevant academic research and scientific papers
π-Facial Diastereoselection in Diels-Alder Reactions of (R)-4-[(p-Tolylsulfinyl)methyl]quinols
Carre?o, M.Carmen,González, Manuel Pérez,Houk
, p. 9128 - 9137 (2007/10/03)
Diels-Alder reactions of a range of (R)-4-hydroxy-4-[(p-tolylsulfinyl)methyl]-2,5-cyclohexadienones with cyclopentadiene and 1,3-pentadiene proceed in a total π-facial diastereoselective manner from the C-4 OH side. Ab initio calculations at the RHF/6-31G
