1027100-93-1

Basic information

• Product Name: C₂₅H₁₆BrNO₂
• Synonyms: C₂₅H₁₆BrNO₂
• CAS NO: 1027100-93-1
• Molecular Weight: 442.312
• Mol File: 1027100-93-1.mol

Chemical Properties

• CAS DataBase Reference: C₂₅H₁₆BrNO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₅H₁₆BrNO₂(1027100-93-1)
• EPA Substance Registry System: C₂₅H₁₆BrNO₂(1027100-93-1)

Safety Data

• Hazardous Substances Data: 1027100-93-1(Hazardous Substances Data)

Upstream product

• 945722-29-2 C₁₈H₁₄O₂ 
• 121554-10-7 5-bromo-2-iodobenzonitrile 

Relevant articles and documents

Rod-shaped oligophenyleneethynylenes modified by donor and acceptor groups in a block manner: Synthesis and light-emitting characteristics

Highly efficient blue light emmitters represented by BL-5 (Φf = 0.96, λem = 455 nm in CHC13) and BL-8 (Φf = 0.98, λem = 464nm in CHCl3) are created by block modification of oligophenylene ethynylenes with donor and acceptor groups. A linear relationship with positive slope between Φf and the movability of the energetically equivalent dipolar structure unit is found for the first time. Copyright

Block modification of rod-shaped π conjugated carbon frameworks with donor and acceptor groups toward highly fluorescent molecules: Synthesis and emission characteristics

To create organic molecules that are highly fluorescent at a longer wavelength region, we investigated the synthesis (using Pd-catalyzed cross-coupling) and photophysical properties (Φ f, λ em, τ , λ abs, and ε ) of the following π conjugated molecular rods consisting of p-phenyleneethynylene units modified by donor (OMe) and/or acceptor (CN) groups: (1) side-donor modification systems (SD systems), (2) side-acceptor modification systems (SA systems), and (3) systems consisting of a donor block and an acceptor block (BL systems). As a consequence, very high Φ f values (>0.95) were obtained for BL systems. Bathochromic shifts of λ em for the same π conjugation length were largest for BL systems. Thus we succeeded in creating highly efficient light emitters at a longer wavelength region by block modification (e.g., Φ f = 0.97, λ em = 464 nm for BL-9). Considerably intense solid emission (Φ f ～ 0.5) at a longer wavelength region (500- 560 nm) was also found for BL systems. It has been found that BL-6 and BL-8 exhibit interesting two photon absorption characteristics. This journal is The Royal Society of Chemistry.