102717-31-7Relevant articles and documents
A General Synthetic Route to A-Ring Hydroxylated Vitamin D Analogs from Pentoses
Moriarty, Robert M.,Kim, Joonggon,Brumer, Harry
, p. 51 - 54 (2007/10/02)
The enyne needed for coupling to a CD-ring fragment, namely, 3S,5R-oct-1-en-7-yne-3,5-diol, in the Trost-Dumas carbopalladation route to 1α,25-dihydroxyvitamin D3 was synthesized from D-xylose in 13 steps and 21percent yield.
The Synthesis of the δ-Lactone Portion of the Mevinic Acids; a New Non-acidic Method of Cyclic Lactone Expansion
Davidson, Alan H.,Floyd, Chris D.,Lewis, Christopher N.,Myers, Peter. L.
, p. 1417 - 1418 (2007/10/02)
An alkoxy-mercuration demercuration sequence has been used as the key step in an enantiospecific synthesis of a protected synthon for the lactone portion of the mevinic acids.