102717-49-7

Upstream product

• 89821-78-3 allyl 4-O-benzyl-α-L-rhamnopyranoside 
• 74-88-4 methyl iodide 
• 475672-25-4 allyl L-rhamnopyranoside 
• 100639-25-6 allyl 2,3-O-isopropylidene-α-L-rhamnopyranoside 
• 89821-77-2 Allyl 4-O-benzyl-2,3-O-isopropylidene-α-L-rhamnopyranoside 

Downstream Products

• 214403-10-8 allyl 2-O-(4-O-acetyl-2,3-di-O-methyl-α-L-rhamnopyranosyl)-4-O-benzyl-3-O-methyl-α-L-rhamnopyranoside 
• 214403-11-9 allyl 2-O-(2,3-di-O-methyl-α-L-rhamnopyranosyl)-4-O-benzyl-3-O-methyl-α-L-rhamnopyranoside 

Relevant academic research and scientific papers

Synthesis of the hyper-branched core tetrasaccharide motif of chloroviruses

Chemical synthesis of complex oligosaccharides, especially those possessing hyper-branched structures with one or multiple 1,2-cisglycosidic bonds, is a challenging task. Complementary reactivity of glycosyl donors and acceptors and proper tuning of the s

Synthesis and NMR analysis of 13C-labeled oligosaccharides corresponding to the major glycolipid from Mycobacterium leprae

An improved synthesis of propyl 4-O-(3,6-di-O-methyl-β-D- glucopyranosyl)-2,3-di-O-methyl-α-L-rhamnopyranoside, a disaccharide corresponding to the phenolic glycolipid of Mycobacterium leprae using a trichloroacetimidate as a glycosyl donor is described. The synthetic strategy is also applied to the preparation of three corresponding disaccharide analogues containing 13C-labeled methyl groups. The preparation of the trisaccharide, propyl 2-O-[4-O-(3,6-di-O-methyl-β-D-glucopyranosyl)-2,3-di- O-methyl-α-L-rhamnopyranosyl]-3-O-methyl-α-L-rhamnopyranoside is also reported. The di- and tri-saccharides were characterized by 1H and 13C NMR spectroscopy.