1027256-66-1Relevant academic research and scientific papers
Stereoselective synthesis of (E)-1-fluoro-1,3-enynes
Yoshida, Masanori,Yoshikawa, Shuhei,Fukuhara, Tsuyoshi,Yoneda, Norihiko,Hara, Shoji
, p. 7143 - 7148 (2001)
1-Fluoro-1,3-enynes were stereoselectively prepared by the cross-coupling reaction of 1-alkynes with β-fluoroalkenyliodides obtained from (β-fluoroalkenyl)iodonium salts. As the reaction proceeds under mild conditions, polyfunctionalized 1-fluoro-1,3-enyn
Regio- and stereoselective synthesis of fluoroalkadienes using β-fluoroalkenyliodonium salt
Yoshida,Nagahara,Fukuhara,Yoneda,Hara
, p. 2283 - 2288 (2007/10/03)
(E,E)-δ-Fluoro-α,β,γ,δ-unsaturated carbonyl compounds and (3E)-4-fluoro-1,3-dienes were stereoselectively synthesized by the palladium-catalyzed coupling reaction of (2-fluoroalkenyl)(p-tolyl)iodonium fluorides with α,β-unsaturated carbonyl compounds and
Stereo- and regioselective synthesis of (E,E)-δ-fluoro-α,β,γ,δ- unsaturated carbonyl compounds by Heck-type reaction of fluoroalkenyliodonium salts
Yoshida, Masanori,Hara, Shoji,Fukuhara, Tsuyoshi,Yoneda, Norihiko
, p. 3887 - 3890 (2007/10/03)
(E,E)-δ-Fluoro-α,β,γ,δ-unsaturated carbonyl compounds were stereo- and regioselectively obtained by a palladium-catalyzed Heck-type reaction of (E)-2-fluoro-1-iodo-1-alkenyliodonium salts with α,β-unsaturated carbonyl compounds. The stereoselective synthesis of the fluorinated analogue of a biologically active unsaturated fatty acid was also achieved using this reaction. (C) 2000 Elsevier Science Ltd.
