102727-60-6Relevant academic research and scientific papers
Synthetic studies toward marine toxic polyethers. 3. Stereocontrol for segment-A1 of okadaic acid by means of oxymercuration and epoxydation
Isobe,Ichikawa,Goto
, p. 5199 - 5202 (2007/10/02)
Segment-A1 of okadaic acid was synthesized from glucose via an acyclic stereocontrol for C-2 by means of oxymercuration. The stereochemistry was proven by comparison with S and R epoxides which were synthesized selectively by chelational and st
