102761-90-0

Basic information

• Product Name: (2S,3S)-2,3-bis(p-tolylsulfonyloxymethyl)bicyclo<2.2.1>heptane
• CAS NO: 102761-90-0
• Molecular Weight: 464.604
• Mol File: 102761-90-0.mol

Chemical Properties

• CAS DataBase Reference: (2S,3S)-2,3-bis(p-tolylsulfonyloxymethyl)bicyclo<2.2.1>heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-2,3-bis(p-tolylsulfonyloxymethyl)bicyclo<2.2.1>heptane(102761-90-0)
• EPA Substance Registry System: (2S,3S)-2,3-bis(p-tolylsulfonyloxymethyl)bicyclo<2.2.1>heptane(102761-90-0)

Safety Data

• Hazardous Substances Data: 102761-90-0(Hazardous Substances Data)

Upstream product

• 129-64-6 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride 
• 2746-19-2 (1R,2R,6S,7S)-4-oxa-tricyclo[5.2.1.0^2,6]dec-8-ene-3,5-dione 
• 88853-27-4 methyl (5S,6S)-6-endo-(D-arabino-tetritol-1-yl)bicyclo<2.2.1>hept-2-eno-5-exo-carboxylate 
• 78037-77-1 (+)-2-endo-3-exo-Bis(hydroxymethyl)-bicyclo<2.2.1>hept-5-ene 
• 70115-99-0 (2S,3S)-bis(hydroxymethyl)bicyclo<2.2.1>heptane 
• 98-59-9 p-toluenesulfonyl chloride 
• 5062-97-5 bicyclo[2.2.1]heptane-2,3-dimethanol 
• 1200-88-0 norbornene-5,6-dicarboxylic acid 
• 699-96-7 (+/-)-(2-endo,3-exo)-bicyclo[2.2.1]hept-5-eno-2,3-dimethanol 
• 5062-97-5 trans-2,3-bis(hydroxymethyl)norbornane 
• 35436-52-3 exo-cis-2,3-dimethoxycarbonylnorbornane 
• 5062-97-5 cis-exo-2,3-bis(hydroxymethyl)bicyclo<2.2.1>heptane 
• 941567-71-1 (1R,2S,3R,4S)-bicyclo[2.2.1]hept-5-ene-2,3-dimethanol 
• 5062-98-6 cis-endo-2,3-bis(hydroxymethyl)bicyclo<2.2.1>heptane 

Downstream Products

• 37602-64-5 2exo,3exo-dimethyl-norbornane 
• 28626-68-8 2endo,3endo-dimethyl-norbornane 

Relevant articles and documents

CHIRAL SYNTHESIS OF ASYMMETRICALLY TETRA-SUBSTITUTED CYCLOPENTANE DERIVATIVES BY DIELS-ALDER ADDITION OF CYCLOPENTADIENE TO UNSATURATED ACYCLIC-SUGAR DERIVATIVES

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CARBONYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS

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Optical and Neutron Inelastic Scattering Study of 2,3-Dimethylnorbornanes

We have measured the infrared, Raman, and neutron vibrational spectra of the 2,3-dimethylnorbornanes with two CH3 or CD3 groups in the 2- and 3-exo or endo positions.A normal-coordinate analysis has been carried out.No coupling reflecting the strain due to the methyl group appears in the C-CH3 bending and torsional modes of the trans isomer, but appears in the cis-exo isomer (average value 23 cm-1) and in the cis-endo isomer (average value 28 cm-1.The frequencies are used for the determination of the thermodynamic contribution to the standard free energy differences.

Chiral rhodium-diphosphine catalyst capable of catalytic reduction of a tetramisole precursor to give a significant excess of the desired S-(-)isomer, levamisole

A soluble, chiral, rhodium-containing catalyst which permits the catalytic reduction of prochiral 3-acyl-1-(2-alkoxyethyl)-4-phenyl-2-imidazolinones to chiral 3-acylimidazolidinones with a substantial excess of the desired S optical isomer. The 3-acylimidazolidinones may in turn be substantially converted to levamisole, and S isomer of tetramisole. The resolution of tetramisole to remove the R isomer is thus avoided.