102769-20-0

Basic information

• Product Name: 5-(4-Bromo-phenyl)-5-oxo-pentanoyl chloride
• CAS NO: 102769-20-0
• Molecular Weight: 289.556
• Mol File: 102769-20-0.mol

Chemical Properties

• CAS DataBase Reference: 5-(4-Bromo-phenyl)-5-oxo-pentanoyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(4-Bromo-phenyl)-5-oxo-pentanoyl chloride(102769-20-0)
• EPA Substance Registry System: 5-(4-Bromo-phenyl)-5-oxo-pentanoyl chloride(102769-20-0)

Safety Data

• Hazardous Substances Data: 102769-20-0(Hazardous Substances Data)

Upstream product

• 35333-26-7 4-bromo-δ-oxobenzenepentanoic acid 
• 1501-27-5 Pentanedioic acid, monomethyl ester 
• 1501-26-4 methyl 4-(chlorocarbonyl)butyrate 
• 90991-23-4 5-(4-bromophenyl)-5-oxopentanoic acid methyl ester 

Downstream Products

• 90991-23-4 5-(4-bromophenyl)-5-oxopentanoic acid methyl ester 

Relevant articles and documents

Base-Promoted/Gold-Catalyzed Intramolecular Highly Selective and Controllable Detosylative Cyclization

A highly selective, controllable and synthetically useful base-promoted intramolecular detosylative cyclization of bis-N-tosylhydrazones has been achieved, affording N-containing heterocycles and cyclic olefins under transition-metal-free or gold-catalyzed procedures, respectively. Moreover, an effective and practical metal-free or gold-catalyzed approach to synthesize polycyclic aromatic compounds is also reported. Basic cyclizations: A highly selective, controllable, and synthetically useful base-promoted intramolecular detosylative cyclization of bis-N-tosylhydrazones affords N-containing heterocycles and cyclic olefins under transition-metal-free or gold-catalyzed procedures, respectively. Moreover, an effective and practical metal-free or gold-catalyzed approach to synthesize polycyclic aromatic compounds is also reported.

Aspects of Tautomerism. Part 15. Investigations on Oxo-participation in δ-Oxocarboxylic Acid Chlorides during their Formation and Alcoholysis

Oxalyl chloride converts ring-substituted 4-benzoylbutyric acids into a mixture of normal and pseudoacid chlorides by two independent and competing pathways.Pseudoacid chlorides are formed by a concerted 2?+2?+2? pathway.I