10277-53-9Relevant academic research and scientific papers
Highly enantioselective kinetic resolution of trans-2-(phenylthio) cyclohexanol derivatives by immobilized Candida antartica B lipase
Chimni, Swapandeep Singh,Kaur, Kirandeep,Bala, Neeraj
, p. 67 - 74 (2013/10/22)
Candida antartica B (immobilized CAL-B) mediated resolutions of trans-2-(phenylthio)cyclohexanol derivatives using vinyl acetate as acylating agent and MTBE as solvent provide excellent enantioselectivity (up to >99%) and high yield of both the enantiomer
Borax-catalyzed thiolysis of 1,2-epoxides in aqueous medium
Gao, Peng,Xu, Peng-Fei,Zhai, Hongbin
scheme or table, p. 6536 - 6538 (2009/04/06)
A convenient, economical, and practical protocol for borax-catalyzed thiolysis of 1,2-epoxides in aqueous medium has been developed, which has greatly expanded the utility scope of borax in organic synthesis.
Efficient ring-opening reaction of epoxides and aziridines promoted by tributylphosphine in water
Fan, Ren-Hua,Hou, Xue-Long
, p. 726 - 730 (2007/10/03)
Tributylphosphine was found to be an effective promoting reagent for the ring-opening reaction of various epoxides and aziridines with nucleophile to produce corresponding anti-bifunctional products in moderate to excellent yields in water.
Thiol-Oxygen Cooxidation Reactions of Cyclopentene, cis- and trans-But-2-ene, Norbornene, and Norbornadiene
Beckwith, Athelstan L. J.,Wagner, Rudolf D.
, p. 3638 - 3645 (2007/10/02)
Thiol-oxygen cooxidation (TOCO) of olefins, followed by reduction of the initially formed hydroperoxides with triphenylphosphine, affords β-hydroxy sulfides in moderate to good yields.The structures of the major products from cis- and trans-but-2-ene and
