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10277-93-7

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10277-93-7 Usage

Uses

Different sources of media describe the Uses of 10277-93-7 differently. You can refer to the following data:
1. 2-Isopropenylphenol, is a common intermediate for the synthesis of 2,4'-Bisphenol A (B519490).
2. 2-Isopropenylphenol, is a common intermediate for the synthesis of 2,4''-Bisphenol A (B519490).

Check Digit Verification of cas no

The CAS Registry Mumber 10277-93-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,2,7 and 7 respectively; the second part has 2 digits, 9 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 10277-93:
(7*1)+(6*0)+(5*2)+(4*7)+(3*7)+(2*9)+(1*3)=87
87 % 10 = 7
So 10277-93-7 is a valid CAS Registry Number.

10277-93-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-prop-1-en-2-ylphenol

1.2 Other means of identification

Product number -
Other names o-isopropenylphenol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10277-93-7 SDS

10277-93-7Relevant articles and documents

Synthesis of Benzofuranones via Palladium-Catalyzed Intramolecular Alkoxycarbonylation of Alkenylphenols

Hirschbeck, Vera,Fleischer, Ivana

, p. 2854 - 2857 (2018)

Herein, a new catalytic system to synthesize benzofuranones is reported. A palladium-catalyzed intramolecular alkoxycarbonylation is employed to generate 3-substituted-benzofuran-2(3H)-ones from alkenylphenols under mild reaction conditions, linked to an ex situ formation of CO from N-formylsaccharin. The carefully chosen catalytic system enables an efficient reaction with a novel functional group tolerance, despite the high polymerization tendency of the starting material.

Bichromatic Photosynthesis of Coumarins by UV Filter-Enabled Olefin Metathesis

Eivgi, Or,Sutar, Revannath L.,Reany, Ofer,Lemcoff, N. Gabriel

supporting information, p. 2352 - 2357 (2017/07/22)

Herein, we report on a two-step bichromatic synthesis of coumarins involving UV-A and UV-C light. The first step is a UV-A-photoinduced ruthenium-catalyzed cross-metathesis (CM) reaction of 2-nitrobenzyl-protected 2-hydroxystyrenes with acrylates, using an external solution of 1-pyrenecarboxaldehyde as a UV filter. Irradiation in the absence of the filter permanently inhibits the light-activated catalyst due to photocleavage of the photolabile protecting group (PPG) and ensuing phenolate chelation to the ruthenium. The simple removal of the external filter after CM allows further photochemical reactions with UV-C light to achieve more complex architectures, such as the coumarins presented in this work. (Figure presented.).

OH-directed alkynylation of 2-vinylphenols with ethynyl benziodoxolones: A fast access to terminal 1,3-enynes

Finkbeiner, Peter,Kloeckner, Ulrich,Nachtsheim, Boris J.

supporting information, p. 4949 - 4952 (2015/04/14)

The first direct alkynylation of 2-vinylphenols was developed. The rationally optimized hypervalent iodine reagent TIPS-EBX in combination with [(CpRhCl2)2] as a C-H-activating transition metal catalyst enables the construction of a variety of highly substituted 1,3-enynes in high yields of up to 98 %. This novel C-H activation method shows excellent chemoselectivity and exclusive (Z)-stereoselectivity, and it is also remarkably mild and tolerates a variety of functional groups. Furthermore, synthetic modifications of the resulting 1,3-enynes were demonstrated. To our knowledge, this is the first example for an OH-directed C-H alkynylation with hypervalent iodine reagents.

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