1027720-86-0Relevant academic research and scientific papers
4-(Arylsulfonyl)glycals in synthesis. Cation-mediated synthesis of 2,6- disubstituted dihydropyrans
Bailey, Jennifer M.,Craig, Donald,Gallagher, Peter T.
, p. 132 - 134 (1999)
4-(Arylsulfonyl)glycal 9, easily prepared from phenylsulfinic acid, acrolein and 2-phenyloxirane, undergoes efficient, stereoselective S(N)1' reactions on exposure to Lewis acidic reagent systems. Treatment of syn-9 with dimethyldioxirane gives a single glycal epoxide, which also is a substrate for intermolecular C-glycosidation reactions.
