102776-36-3

Upstream product

• 186581-53-3 diazomethane 
• 102776-32-9 (3R,4S)-3-((1R,2R,4R)-1-tert-Butoxymethyl-7,7-dimethyl-bicyclo[2.2.1]hept-2-yloxy)-2,2-dichloro-4-phenethyl-cyclobutanone 
• 102776-23-8 (1R,2R,4R)-1-tert-Butoxymethyl-7,7-dimethyl-2-((Z)-4-phenyl-but-1-enyloxy)-bicyclo[2.2.1]heptane 

Downstream Products

• 102776-43-2 3-(S)-phenethyl cyclopentanone 

Relevant academic research and scientific papers

ASYMMETRIC INDUCTION IN THE CYCLOADDITION REACTION OF DICHLOROKETENE WITH CHIRAL ENOL ETHERS. A VERSATILE APPROACH TO OPTICALLY ACTIVE CYCLOPENTENONE DERIVATIVES.

Significant asymmetric induction has been observed in the cycloaddition reaction of dichloroketene with chiral enol ethers.The resultant diastereomeric cyclobutanones have been converted to synthetically useful α-chlorocyclopentenones in optically active form.