102789-95-7Relevant academic research and scientific papers
Novel Synthesis of α,β-Unsaturated Ketones by the Palladium-Catalyzed Arylation of Ketenes with Aroyl Chlorides or the Decarbonylative Cross-Condensation of Acyl Halides
Mitsudo, Take-aki,Kadokura, Mamoru,Watanabe, Yoshihisa
, p. 3186 - 3192 (2007/10/02)
The reaction of alkylphenylketene with aroyl chlorides or the decarbonylative cross-condensation reaction of α-phenylacetyl chlorides with aroyl chlorides in the presence of triethylamine and a catalytic amount of a palladium complex gives α,β-unsaturated
Palladium-catalysed Decarbonylative Cross Condensation of Acyl Halides
Kadokura, Mamoru,Mitsudo, Take-aki,Watanabe, Yoshihisa
, p. 252 - 253 (2007/10/02)
The reaction of alkylphenylacetyl chlorides with aroyl chlorides catalysed by tetrakis(triphenylphosphine)palladium gives α,β-unsatureted ketones selectively via a decarbonylative cross condensation reaction.
PALLADIUM COMPLEX CATALYZED SYNTHESIS OF α,β-UNSATURATED KETONES FROM ALKYLPHENYLKETENE AND AROYL CHLORIDE
Mitsudo, Take-aki,Kadokura, Mamoru,Watanabe, Yoshihisa
, p. 5143 - 5144 (2007/10/02)
α,β-Unsaturated ketones were obtained from alkylphenylketene and aroyl chloride via decarbonylation reaction in the presence of catalytic amounts of tetrakis(triphenylphosphine) palladium.
