1027897-51-3

Basic information

• Product Name: 3-methyl-4-oxo-5-(phenylthio)pentanol hemiketal
• Synonyms: 3-methyl-4-oxo-5-(phenylthio)pentanol hemiketal
• CAS NO: 1027897-51-3
• Molecular Weight: 224.324
• Mol File: 1027897-51-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-methyl-4-oxo-5-(phenylthio)pentanol hemiketal(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-4-oxo-5-(phenylthio)pentanol hemiketal(1027897-51-3)
• EPA Substance Registry System: 3-methyl-4-oxo-5-(phenylthio)pentanol hemiketal(1027897-51-3)

Safety Data

• Hazardous Substances Data: 1027897-51-3(Hazardous Substances Data)

Upstream product

• 13307-75-0 (phenylthio)methyllithium 
• 1679-47-6 3-methyltetrahydro-2-furanone 

Downstream Products

• 173310-53-7 3-methyl-4-oxo-5-(phenylthio)pentanal 

Relevant articles and documents

and Annulation Reactions of α-(Phenylthio) Dicarbonyl Electrophiles with Bis(trimethylsilyl) Enol Ethers: Synthesis of Highly Functionalized Medium Ring Cycles

The and annulations of bis(trimethylsilyl) enol ethers with 1,4- and 1,5-dicarbonyl electrophiles bearing α-phenylthio substituents leads to the formation of bicyclic and ethers with good regiochemical and stereochemical control.Subsequent oxidation of the phenylthio moiety followed by reduction with SmI2 constitutes a high-yielding and regioselective process for cleavage of the bridging ether linkage.The overal strategy provides a synthetic pathway for the synthesis of highly functionalized medium ring carbocycles.