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"5',6-Cyclo-5'-deoxy-2',3'-O-isopropylidene-5,6-dihydrouridine" is a complex organic compound that belongs to the class of nucleosides, which are the building blocks of nucleic acids like DNA and RNA. This specific compound features a unique cyclization between the 5' and 6 positions, which is not found in the standard uridine structure. The "5'-deoxy" part of the name indicates the absence of an oxygen atom at the 5' position, which is a modification that can affect the compound's chemical properties and interactions. The "2',3'-O-isopropylidene" part refers to the protection group used in organic synthesis, which involves the formation of a cyclic acetal between the 2' and 3' hydroxyl groups using isopropylidene. This protection is crucial for preventing unwanted side reactions during chemical synthesis. The "5,6-dihydrouridine" portion signifies that the compound has undergone reduction at the 5 and 6 positions, which can alter its reactivity and biological activity. Overall, 5',6-Cyclo-5'-deoxy-2',3'-O-isopropylidene-5,6-dihydrouridine is of interest in the field of chemistry and biochemistry due to its potential applications in the development of new drugs and the study of nucleic acid chemistry.

1028-88-2

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1028-88-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1028-88-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,0,2 and 8 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1028-88:
(6*1)+(5*0)+(4*2)+(3*8)+(2*8)+(1*8)=62
62 % 10 = 2
So 1028-88-2 is a valid CAS Registry Number.

1028-88-2Downstream Products

1028-88-2Relevant academic research and scientific papers

Synthesis of 5′,8-cyclopurine and of 5′,6-cyclodihydropyrimidine nucleosides using intramolecular radical cyclisation based on the aryl telluride radical exchange process

Barton, Derek H. R.,Gero, Stephane D.,Quiclet-Sire, Beatrice,Samadi, Mohammad,Vincent, Claire

, p. 9383 - 9392 (2007/10/02)

The synthesis of C-cyclopurine and C-cyclodihydropyrimidine nucleosides has been effected using 5′-aryltelluronucleosides. Generation of methyl radicals from the photolysis of the acetyl derivative of N-hydroxy-2-thiopyridone permitted, by radical exchang

A NOVEL STEREOSPECIFIC RADICAL CYCLIZATION OF 2',3'-O-ISOPROPYLIDENEURIDE AND -ADENOSINE 5'-ALDEHYDE TO THE CORRESPONDING 6,5'-CYCLODIHYDROURIDINE AND 8,5'-CYCLOADENOSINE DERIVATES

Sugawara, Tomokazu,Otter, Brian A.,Ueda, Tohru

, p. 75 - 78 (2007/10/02)

Treatment of 2',3'-O-isopropylideneuridine 5'-aldehyde with tributyltin hydride in the presence of azobisisobutyronitrile affords (6S,5'S)-cyclo-5,6-dihydro-2',3'-O-isopropylideneuridine in a stereospecific manner.A similar reaction with N6-benzoyl-2',3'-O-isopropylideneadenosine 5'-aldehyde leads to the corresponding 8,5'-cycloadenosine.

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