102804-47-7

Basic information

• Product Name: 2-Propenamide, N-(2-bromophenyl)-N-methyl-
• CAS NO: 102804-47-7
• Molecular Formula: C10H10BrNO
• Molecular Weight: 240.099
• Mol File: 102804-47-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Propenamide, N-(2-bromophenyl)-N-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenamide, N-(2-bromophenyl)-N-methyl-(102804-47-7)
• EPA Substance Registry System: 2-Propenamide, N-(2-bromophenyl)-N-methyl-(102804-47-7)

Safety Data

• Hazardous Substances Data: 102804-47-7(Hazardous Substances Data)

Upstream product

• 615-36-1 2-bromoaniline 
• 102804-43-3 N-(2-bromophenyl)acrylamide 
• 74-88-4 methyl iodide 

Downstream Products

• 34191-69-0 3-(4-methoxybenzyl)-1-methylindolin-2-one 
• 3335-85-1 3-benzyl-1-methyl-1,3-dihydroindol-2-one 
• 24438-17-3 1,3-dimethylindolin-2-one 
• 826-72-2 N-methyldihydrocarbostyril 
• 5827-78-1 N-methyl-N-phenylpropanamide 

Relevant articles and documents

Rh-Catalyzed Domino Addition-Enolate Arylation: Generation of 3-Substituted Oxindoles via a Rh(lll) Intermediate

A Rh-catalyzed domino conjugate addition-arylation sequence via a Rh(III) intermediate is reported. This process involving a proposed intramolecular oxidative addition of a rhodium enolate was utilized to achieve the synthesis of 3-substituted oxindole derivatives in moderate to excellent yields.

An Efficient Synthesis of Spiro via Radical Cyclisation

Treatment of the o-bromo-N-acryloylanilides (4) with tri-n-butylstannane leads to the formation of 3-substituted- and 3,3-disubstituted-2-oxindoles (5) in high yield.