1028049-92-4Relevant academic research and scientific papers
Nickel-catalyzed coupling of fluoroarenes and amines
Zhu, Feng,Wang, Zhong-Xia
, p. 3694 - 3702 (2014/01/06)
The combination of bis(cyclooctadiene)nickel [Ni(COD)2] and 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride (IPr×HCl) effectively catalyzes coupling of fluoroarenes with amines in the presence of sodium tert-butoxide (t-BuONa). A
Nickel-catalyzed amination of aryl Pivalates by the cleavage of aryl C-O bonds
Shimasaki, Toshiaki,Tobisu, Mamoru,Chatani, Naoto
supporting information; experimental part, p. 2929 - 2932 (2010/06/15)
(Figure Presented) Catalytic animation: The title reaction demonstrates the use of aryl carboxylates as suitable electrophilic coupling substrates in catalytic amination reactions. Nheterocyclic carbene ligands and NaOtBupromote the amination of aryl pivalates through the cleavage of normally unreactive aryl carbon-oxygen bonds (see scheme; cod = cyclooctadiene).
