1028191-94-7

Basic information

• Product Name: 2-azido-3,5-O-benzylidene-1-bromo-1,2-dideoxy-4-O-formyl-1-iodo-D-arabinitol
• Synonyms: 2-azido-3,5-O-benzylidene-1-bromo-1,2-dideoxy-4-O-formyl-1-iodo-D-arabinitol
• CAS NO: 1028191-94-7
• Molecular Weight: 482.072
• Mol File: 1028191-94-7.mol

Chemical Properties

• CAS DataBase Reference: 2-azido-3,5-O-benzylidene-1-bromo-1,2-dideoxy-4-O-formyl-1-iodo-D-arabinitol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-azido-3,5-O-benzylidene-1-bromo-1,2-dideoxy-4-O-formyl-1-iodo-D-arabinitol(1028191-94-7)
• EPA Substance Registry System: 2-azido-3,5-O-benzylidene-1-bromo-1,2-dideoxy-4-O-formyl-1-iodo-D-arabinitol(1028191-94-7)

Safety Data

• Hazardous Substances Data: 1028191-94-7(Hazardous Substances Data)

Downstream Products

• 1028192-00-8 (1E)-2-azido-3,5-O-benzylidene-1-bromo-1,2-dideoxy-4-O-formyl-D-erythro-pent-1-enitol 
• 1028192-01-9 (1Z)-2-azido-3,5-O-benzylidene-1-bromo-1,2-dideoxy-4-O-formyl-D-erythro-pent-1-enitol 

Relevant articles and documents

Synthesis of polyhydroxylated 2H-azirines and 2-halo-2H-azirines from 3-azido-2,3-dideoxyhexopyranoses by alkoxyl radical fragmentation

(Chemical Equation Presented) The reaction of 3-azido-2,3-dideoxypyranose and 3-azido-2,3-dideoxy-2-halohexopyranose compounds with (diacetoxyiodo)benzene and iodine generated 2-azido-1,2-dideoxy-1-iodoalditols and 2-azido-1,2-dideoxy-1-halo-1-iodoalditols, respectively. These β-iodo azides could be transformed by chemoselective dehydroiodination into 2-azido-1,2-dideoxy-4-O-formyl-pent-1-enitols and (Z,E)-2-azido-1,2-dideoxy-1- halo-4-O-formyl-pent-1-enitols in good yields. Thermolysis and photochemical studies of these vinyl azides and 1-halovinyl azides for the synthesis of polyhydroxylated 3-alkyl-2H-azirines and the hitherto unknown 2-halo-3-alkyl-2H-azirines have also been accomplished.