1028206-60-1

Basic information

• Product Name: Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine-κP]chloro-, (SP-4-4)-
• Synonyms: Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II), methyl-t-butylether adduct, min. 98%;Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II), methyl-t-butylether adduct, min. 98% [RuPhos Palladacycle];(2-Dicyclohexylphosphino-2′,6′-diisopropyl-1,1′-biphenyl)[2-(2-aminoethyl)phenyl)]palladium(II);Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)[2-(2-aMinoethylphenyl)]palladiuM(II),Methyl-t-butyletheradduct,Min.98%;Chloro(2-dicyclohexylphosphino-2',6'-diisopropoxy-1,1-biphenyl)[2-(2-aminoethylphenyl)]palladium(II);Chloro(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)[2-(2-aMinoethylphenyl)]palladiuM(II), Methyl-t-butylether adduct,98% RuPhos Palladacycle
• CAS NO: 1028206-60-1
• Molecular Formula: C38H53ClNO2PPd
• Molecular Weight: 816.827861
• Mol File: 1028206-60-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine-κP]chloro-, (SP-4-4)-(CAS DataBase Reference)
• NIST Chemistry Reference: Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine-κP]chloro-, (SP-4-4)-(1028206-60-1)
• EPA Substance Registry System: Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine-κP]chloro-, (SP-4-4)-(1028206-60-1)

Safety Data

• Hazardous Substances Data: 1028206-60-1(Hazardous Substances Data)

Usage

Reaction

Catalyst used in the thermal dehydrogenative Diels-Alder reaction of styrenes. Catalyst used for the CN-cross coupling reactions of 3-halo-2-aminopyridines. Catalyst used for the domino reaction of two aryl iodides, involving two C-H functionizations.

Upstream product

• 13078-80-3 2-(2-chlorophenyl)ethanamine 
• 787618-22-8 ruphos 

Relevant articles and documents

A new class of easily activated palladium precatalysts for facile C-N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides

A new class of one-component Pd precatalysts bearing biarylphosphine ligands is described. These precatalysts are air- and thermally stable, are easily activated under normal reaction conditions at or below room temperature, and ensure the formation of the highly active monoligated Pd(0) complex necessary for oxidative addition. The use of these precatalysts as a convenient source of LPd(0) in C-N cross-coupling reactions is explored. The reactivity that is demonstrated in this study is unprecedented in palladium chemistry. Copyright