102829-48-1Relevant academic research and scientific papers
REVERSIBLE CARBON-CARBON BOND FORMATION BY INTERCONVERSION OF CO AND μ-ACYL LIGANDS ON THE FACE OF AN OSMIUM CLUSTER
Koridze, A. A.,Kizas, O. A.,Kolobova, N. E.,Petrovskii, P. V.
, p. C1 - C3 (1985)
Addition of PMe2Ph to the μ-acyl complex (III) induces carbon-carbon bond cleavage with conversion of the μ-acyl group to a terminal CO ligand and gives the zwitterionic compound (IV).Facile elimination of CO (or PMe2Ph) from IV at the rhenium atom leads to the back formation of a μ-acyl group and gives the complex (V) or complex III.
