1028491-25-9Relevant academic research and scientific papers
An unusually stable octanuclear σ-mesityl-bridged μ4-oxo-copper(i) complex encapsulated by a pyrazolate-based compartmental ligand scaffold
Stollenz, Michael,Grosse, Christian,Meyer, Franc
, p. 1744 - 1746 (2008/12/22)
A new compartmental pyrazole-derived chelating ligand, four equivalents of mesitylcopper and stoichiometric amounts of dioxygen lead to the formation of a remarkably stable organometallic framework that can be described as a heteroleptic O-centered cuprate anion [(MesCuI) 4(μ4-O)]2- linked via σ-mesityl- bridges to two surrounding binuclear CuI-pyrazolate clamps. The Royal Society of Chemistry.
