102851-23-0

Basic information

• Product Name: 5-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-8-(2-methoxy-phenyl)-bicyclo[4.2.0]octa-1,3,5-trien-7-one
• Synonyms: 5-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-8-(2-methoxy-phenyl)-bicyclo[4.2.0]octa-1,3,5-trien-7-one
• CAS NO: 102851-23-0
• Molecular Weight: 370.521
• Mol File: 102851-23-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-8-(2-methoxy-phenyl)-bicyclo[4.2.0]octa-1,3,5-trien-7-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-8-(2-methoxy-phenyl)-bicyclo[4.2.0]octa-1,3,5-trien-7-one(102851-23-0)
• EPA Substance Registry System: 5-(tert-Butyl-dimethyl-silanyloxy)-8-hydroxy-8-(2-methoxy-phenyl)-bicyclo[4.2.0]octa-1,3,5-trien-7-one(102851-23-0)

Safety Data

• Hazardous Substances Data: 102851-23-0(Hazardous Substances Data)

Upstream product

• 102808-59-3 3-(tert-butyldimethylsiloxy)benzocyclobutenedione 
• 16750-63-3 2-methoxyphenylmagnesium bromide 

Downstream Products

• 52869-21-3 1-hydroxy-5-methoxy-9,10-anthraquinone 

Relevant articles and documents

A General, Regiospecific Synthesis of Highly Substituted Quinones

A general route to a wide variety of substituted quinones (furyl, indolo, pyrrolo, quinolino, naphtho, and anthra) has been developed via the thermolysis (160 deg C, xylene) and subsequent oxidation (air or Ce4+) of 4-hydroxy-4-substituted-cyclobutenones (eq. 1) and 2-hydroxy-2-substituted-benzocyclobutenones which were formed by the regioselective addition of an appropriate aryl or heteroaryl (etc.) lithium reagent to the correspnding cyclobutenedione.