102878-75-1

Basic information

• Product Name: Benzene, 2-ethyl-4-methyl-1-nitro-
• CAS NO: 102878-75-1
• Molecular Formula: C9H11NO2
• Molecular Weight: 165.192
• Mol File: 102878-75-1.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 2-ethyl-4-methyl-1-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 2-ethyl-4-methyl-1-nitro-(102878-75-1)
• EPA Substance Registry System: Benzene, 2-ethyl-4-methyl-1-nitro-(102878-75-1)

Safety Data

• Hazardous Substances Data: 102878-75-1(Hazardous Substances Data)

Upstream product

• 620-14-4 1-Methyl-3-ethylbenzene 
• 102878-74-0 2-methyl-6-ethylnitrobenzene 
• 873386-58-4 acetic acid-(4-ethyl-2-methyl-5-nitro-anilide) 
• 112825-83-9 {1-[1-Nitro-meth-(Z)-ylidene]-propylsulfanyl}-benzene 
• 112825-85-1 C₁₆H₁₇NO₂S₂ 
• 446-34-4 2-fluoro-4-methyl-1-nitrobenzene 
• 7664-93-9 sulfuric acid 
• 7697-37-2 nitric acid 
• 52062-24-5 (E)-1-acetoxy-3-methyl-1,3-butadiene 
• 112825-82-8 ((Z)-1-Nitro-but-1-ene-2-sulfinyl)-benzene 
• 872275-09-7 4-ethyl-2-methyl-5-nitro-aniline 
• 871878-96-5 acetic acid-(4-ethyl-2-methyl-anilide) 

Downstream Products

• 103858-41-9 acetic acid-(2-ethyl-4-methyl-anilide) 
• 24544-07-8 2-ethyl-4-methylaniline 

Relevant articles and documents

Bis(dealkoxycarbonylation) of nitroarylmalonates: A facile entry to alkylated nitroaromatics

A simple approach to alkylated nitroaromatics from substituted nitroaryl malonic esters by double decarboxylation is detailed.

THE CYCLISATION AND REARRANGEMENT OF THE NITRO DERIVATIVES OF AROMATIC HYDROCARBONS IN TRIFLUOROMETHANESULPHONIC ACID

A number of the nitro derivatives of aromatic hydrocarbons undergo reactions in trifluoromethanesulphonic acid at ca. 100 deg C in which either the nitro group undergoes a 1,3-rearrangement or cyclisation occurs to form an anthranil.The rates and product composition have been determined for reactions in which the subsituents ortho to the nitro group are methyl or ethyl.For the rearrangement reaction to occur, it appears necessary that the nitro group should be initially between two alkyl substituents.The cyclisation reaction is significant only when one of the ortho-substituents is an ethyl group.

Nitroacetylene Equivalents. Preparation and Cycloadditions of 2-Phenylsulphinyl-1-nitroalkenes

β-Phenylsulphinyl-nitro-alkenes (7) are readily prepared from acyl imidazoles and react as nitroacetylene equivalents in Diels-Alder reactions to give good yields of cycloadducts and their further products.