10289-68-6

Basic information

• Product Name: 3-TRIDECANOL
• Synonyms: 3-TRIDECANOL;tridecan-3-ol
• CAS NO: 10289-68-6
• Molecular Formula: C₁₃H₂₈O
• Molecular Weight: 200.36
• EINECS: 233-640-6
• Mol File: 10289-68-6.mol
• Article Data: 9

Chemical Properties

• Melting Point: 32°C
• Boiling Point: 268.11°C (estimate)
• Flash Point: 105.5°C
• Appearance: /
• Density: 0.7947 (estimate)
• Vapor Pressure: 0.00173mmHg at 25°C
• Refractive Index: 1.4192 (estimate)
• PKA: 15.27±0.20(Predicted)
• CAS DataBase Reference: 3-TRIDECANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 3-TRIDECANOL(10289-68-6)
• EPA Substance Registry System: 3-TRIDECANOL(10289-68-6)

Safety Data

• Hazardous Substances Data: 10289-68-6(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 55, p. 788, 1990 DOI: 10.1021/jo00290a004

InChI:InChI=1/C13H28O/c1-3-5-6-7-8-9-10-11-12-13(14)4-2/h13-14H,3-12H2,1-2H3

Upstream product

• 1534-26-5 3-tridecanone 
• 41446-59-7 (Z)-tridec-2-ene 
• 54795-48-1 1-(toluene-4-sulfonyloxy)-tridecan-3-ol 
• 71-23-8 propan-1-ol 
• 872-05-9 1-Decene 
• 2874-75-1 2-ethyldodecanoic acid 
• 112-37-8 undecylenic acid 
• 74963-02-3 trans-2,3-Epoxy-1-tridecanol 
• 2855-19-8 Decyl-oxiran 
• 917-54-4 methyllithium 
• 676-58-4 methylmagnesium chloride 
• 17049-50-2 n-decyl magnesium bromide 
• 123-38-6 propionaldehyde 
• 139926-07-1 trans-2,3-Epoxy-1-tridecanol mesylate 

Downstream Products

• 1534-26-5 3-tridecanone 

Relevant articles and documents

Diacetyl atractylodiol, a new acetylenic compound from Atractylodes japonica Koidzumi

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Hydrofunctionalization of Olefins to Higher Aliphatic Alcohols via Visible-Light Photocatalytic Coupling

Abstract: An atomically economical green protocol for the hydrofunctionalization of olefins to higher aliphatic alcohols with 100% anti-Markovnikov regioselectivity was developed via visible-light photocatalytic coupling. This method employs cheap, readily available and abundant methanol as both the C1 feedstock and the hydrogen source under visible light irradiation over CdS photocatalyst. A wide scope of olefin substrates could be hydrofunctionalized successfully to the corresponding higher alcohols with high selectivity. Besides alcohol, acetone and acetonitrile can also couple with olefins to generate the corresponding hydrofunctionalization products, suggesting promising potential industrial application. Graphical Abstract: [Figure not available: see fulltext.] Hydrofunctionalization of olefins to value-added chemicals with high selectivity was achieved via visible-light photocatalytic cross-coupling.

Tandem isomerization/hydroformylation/hydrogenation of internal alkenes to n-alcohols using Rh/Ru dual-or ternary-catalyst systems

A one-pot three-step reaction, isomerization/hydroformylation/hydrogenation of internal alkenes to n-alcohols, was accomplished by employing a Rh/Ru dual-catalyst system. By using a combination of Rh(acac)(CO)2/ bisphosphite and Shvo's catalyst, (Z)-2-tridecene was converted to 1-tetradecanol in 83% yield with high normal/iso selectivity (n/i = 12). The method was applicable to other internal alkenes, including functionalized alkenes, such as an alkenol and an alkenoate. Furthermore, addition of a third component, Ru3(CO)12, effectively improved the n/i ratio in the tandem isomerization/hydroformylation/hydrogenation of methyl oleate (from n/i = 1.9 to 4.4). Control experiments revealed that the isomerization was mediated by both Rh and Ru and that the coexistence of Rh and Ru was essential for hydrogenation of aldehyde under H2/CO.