1029010-53-4Relevant academic research and scientific papers
Catalytic enantioselective addition of diorganozinc reagents to vinyl sulfones
Desrosiers, Jean-Nicolas,Bechara, William S.,Charette, Andre B.
supporting information; experimental part, p. 2315 - 2318 (2009/05/26)
(Chemical Equation Presented) An efficient method for the catalytic asymmetric conjugate addition of diorganozinc reagents to vinyl sulfones is reported. Using a Binap·Cu complex, enantioselectivities up to 98% ee and high yields can be attained for a variety of substrates. Several dialkylzinc reagents are also compatible with this procedure.
