10293-06-8Relevant articles and documents
Ranganathan,Raman
, p. 411 (1973)
New chiral cyclopalladated complexes based on the pinane and bornane imines
Kuchin,Gur'eva,Frolova,Alekseev,Zalevskaya
, p. 745 - 750 (2014/01/23)
2α-Hydroxypinan-3-one imino derivatives react with lithium tetrachloropalladate to form palladacycles, while similar bornane derivative undergo cyclopalladation only when treated with palladium acetate.
REACTIVITY OF 3-BROMOCAMPHOR AND 3-BROMOISOCAMPHANONE UNDER THE CONDITIONS OF THE RITTER REACTION
Koval'skaya, S. S.,Kozlov, N. G.,Zyryanov, V. A.
, p. 722 - 726 (2007/10/02)
The bromination of camphor and isocamphanone yield, respectively, 3-endo- and 3-exo-bromo ketones.Under the conditions of the Ritter reaction 3-bromocamphor does not react with nitriles, while 3-isocamphanone is selectively converted into the corresponding N,N'-diacyl-3-bromo-2,2-gem-diamino-5,5,6-trimethylbicycloheptanes.
ENANTIOSPECIFIC SYNTHESIS OF ESTRONE
Hutchinson, John H.,Money, Thomas
, p. 1 - 6 (2007/10/02)
Efiicient cleavage of the C(1)-C(2) bond in 9,10-dibromocamphor (3) provides a chiral intermediate (5) that can be used in a new enantiospecific synthesis of estrone.