1029612-76-7

Basic information

• Product Name: (Z)-ethyl 3-phenyl-2-hexenoate
• Synonyms: (Z)-ethyl 3-phenyl-2-hexenoate
• CAS NO: 1029612-76-7
• Molecular Weight: 218.296
• Mol File: 1029612-76-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (Z)-ethyl 3-phenyl-2-hexenoate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-ethyl 3-phenyl-2-hexenoate(1029612-76-7)
• EPA Substance Registry System: (Z)-ethyl 3-phenyl-2-hexenoate(1029612-76-7)

Safety Data

• Hazardous Substances Data: 1029612-76-7(Hazardous Substances Data)

Upstream product

• 495-40-9 propiophenone 
• 87666-32-8 (E)-ethyl 3-phenyl-2-hexenoate 
• 1029612-24-5 C₁₅H₂₀O₅S 
• 100-58-3 phenylmagnesium bromide 
• 18819-63-1 (E)-3-chloro-3-phenyl-2-propenoic acid 
• 55164-20-0 ethyl-(E)-3-chloro-3-phenyl-2-propenoate 

Relevant articles and documents

Energy-Transfer-Mediated Photocatalysis by a Bioinspired Organic Perylenephotosensitizer HiBRCP

Energy transfer plays a special role in photocatalysis by utilizing the potential energy of the excited state through indirect excitation, in which a photosensitizer determines the thermodynamic feasibility of the reaction. Bioinspired by the energy-transfer ability of natural product cercosporin, here we developed a green and highly efficient organic photosensitizer HiBRCP (hexaisobutyryl reduced cercosporin) through structural modification of cercosporin. After structural manipulation, its triplet energy was greatly improved, and then, it could markedly promote the efficient geometrical isomerization of alkenes from the E-isomer to the Z-isomer. Moreover, it was also effective for energy-transfer-mediated organometallic catalysis, which allowed realization of the cross-coupling of aryl bromides and carboxylic acids through efficient energy transfer from HiBRCP to nickel complexes. Thus, the study on the relationship between structural manipulation and their photophysical properties provided guidance for further modification of cercosporin, which could be applied to more meaningful and challenging energy-transfer reactions.

General, robust, and stereocomplementary preparation of β-ketoester enol tosylates as cross-coupling partners utilizing TsCl-N-methylimidazole agents

(Chemical Equation Presented) We have developed a general, robust, and cost-effective method for the (E)- or (Z)-stereocomplementary enol tosylation of β-ketoesters using TsCl-N-methylimidazole (NMI)-Et3N or LiOH. TsCl coupled with NMI formed a