1029690-64-9Relevant academic research and scientific papers
Vanadium(V) hydrazido(2-) thiolate imine alkoxide complexes
Banerjee, Sanjukta,Odom, Aaron L.
, p. 2005 - 2008 (2008/09/20)
The reaction of (Me3Si)2TIP with V(NNMe 2)(OAr)3 results in the production of V(NNMe 2)(TIP)(OAr), where TIP is 2-((2-thiolatophenylimino)methylene) phenolate. The aryloxide is readily displaced by ISiMe3 to form an insoluble iodide complex formulated as V(NNMe2)(TIP)(I). The iodide was used to prepare three different complexes: [V(NNMe2)(TIP)(dmpe)] I, [V(NNMe2)(TIP)(Butbpy)][OTf], and [V(NNMe 2)(TIP)(Butbpy)][SbF6]. The phosphine derivative, [V(NNMe2)(TIP)(dmpe)]I, was characterized by X-ray diffraction and shows a quite short N-N distance of 1.293(3) A indicative of a dominant isodiazene resonance form. The Royal Society of Chemistry.
