1029801-33-9Relevant articles and documents
Rhodium(I)-catalyzed cycloisomerizations of bicyclobutanes
Walczak, Maciej A. A.,Wipf, Peter
, p. 6924 - 6925 (2008/09/21)
The selection of rhodium precatalyst and phosphine ligand determines the course of the cycloisomerization of N-allylated bicyclo[1.1.0]butylalkylamines. Cyclopropane-fused pyrrolidines and azepines are obtained with high levels of stereo- and regiocontrol. Novel azatricyclo[6.1.0.01,5]nonanes are the result of a tandem cycloisomerization-ring closing metathesis sequence. Allylic ethers lead to furans and oxepanes. Copyright