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[Ir(P(C6H11)3)2(SO)Cl] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

102983-27-7

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102983-27-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 102983-27-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,2,9,8 and 3 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 102983-27:
(8*1)+(7*0)+(6*2)+(5*9)+(4*8)+(3*3)+(2*2)+(1*7)=117
117 % 10 = 7
So 102983-27-7 is a valid CAS Registry Number.

102983-27-7Downstream Products

102983-27-7Relevant academic research and scientific papers

Four- and Five-Coordinated Sulfur Monoxide Complexes of Rhodium and Iridium

Schenk, Wolfdieter A.,Leissner, Johanna,Burschka, Christian

, p. 1264 - 1273 (2007/10/02)

The complexes trans- (M = Rh, Ir; R = isopropyl, cyclohexyl) were synthesized from 2, PR3 and C2H4SO.The X-ray structure of shows the sulfur monoxide to be coordinated in a bent η1 fashion.A bonding model is proposed which explains the similarity between SO- and SO2-complexes.Peracid oxidation transforms coordinated SO to SO2.CO displaces SO via isolable 5-coordinated intermediates . - Key words: Sulfur Monoxide Complexes, Synthesis, Structure, Bonding, Peracid Oxidation, SO-Displacement

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