103-23-1 Usage
Chemical Properties
colourless oily liquid
Uses
Different sources of media describe the Uses of 103-23-1 differently. You can refer to the following data:
1. The compound is used as a plasticizer for
flexible vinyl food wraps and as a solvent for aircraft
lubricants.
2. Plasticizer in polyvinyl chloride films,
sheeting, extrusions, and plastisols; solvent and
emollient in cosmetics
3. Bis(2-ethylhexyl) adipate also known as dioctyl adipate (DOA) can be used as a plasticizer for improving the impact properties of polymers. DOA is also used to produce clear films for food packaging applications and in synthetic rubber industries due to its compatibility with nitrocellulose and ethylcellulose.
Definition
ChEBI: A diester resulting from the formal condensation of the carboxy groups of adipic acid with 2-ethylhexan-1-ol. It is used as a plasticiser in the preparation of various polymers.
Production Methods
DEHA is manufactured by esterification of adipic acid and
2-ethylhexanol.
General Description
Colorless to straw-colored liquid with a mild odor. Floats on water.
Air & Water Reactions
Bis(2-ethylhexyl) adipate slowly hydrolyzes. Insoluble in water.
Reactivity Profile
Bis(2-ethylhexyl) adipate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Can generate electrostatic charges. [Handling Chemicals Safely 1980. p. 250]. Bis(2-ethylhexyl) adipate is incompatible with oxidizing materials and water. Bis(2-ethylhexyl) adipate is also incompatible with nitrates.
Health Hazard
Liquid may cause mild eye irritation. Repeated or prolonged skin contact may cause irritation.
Fire Hazard
Behavior in Fire: Use water spray to cool exposed containers.
Flammability and Explosibility
Nonflammable
Safety Profile
Moderately toxic by intravenous route. Mildly toxic by ingestion. Experimental reproductive effects. Mutation data reported. An eye and skin irritant. Questionable carcinogen with experimental carcinogenic data. See also ESTERS. When heated to decomposition it emits acrid smoke and irritating fumes.
Check Digit Verification of cas no
The CAS Registry Mumber 103-23-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 3 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 103-23:
(5*1)+(4*0)+(3*3)+(2*2)+(1*3)=21
21 % 10 = 1
So 103-23-1 is a valid CAS Registry Number.
InChI:InChI=1/C22H42O4/c1-5-9-13-19(7-3)17-25-21(23)15-11-12-16-22(24)26-18-20(8-4)14-10-6-2/h19-20H,5-18H2,1-4H3/t19-,20+
103-23-1Relevant articles and documents
Nano-SO42-/TiO2catalyzed eco-friendly esterification of dicarboxylic acids
Ji, Xianbing,Chen, Yinxia,Shen, Zuoyuan
, p. 5769 - 5772 (2014)
Nano-SO42-/TiO2 was prepared by wet impregnation method. The structure and properties of the prepared nano-SO42-/TiO2catalyst was characterized by XRD, SEM, TEM and BET analysis. The catalytic activities of the catalysts were tested by the esterification of sebacic acid with 2-ethyl hexanol and a series of other dicarboxylic acid. The influence factors on the reaction, such as the catalyst calcination temperature, reaction temperature/time and the molar ratio of acid to alcohol were extensively explored. Nano-SO42-/TiO2prepared exhibited much higher catalytic activity in esterification reactions. By applying the optimized reaction condition, i.e. 160 C, 2 h, 5 wt % nano-SO42-/TiO2with a 1:3 molar ratio of sebacic acid to 2-ethyl hexanol, higher than 99 % isolated of the desired ester could be obtained.
Micro-flow nanocatalysis: synergic effect of TfOH@SPIONs and micro-flow technology as an efficient and robust catalytic system for the synthesis of plasticizers
Tashi, Maryam,Shafiee, Behnaz,Sakamaki, Yoshie,Hu, Ji-Yun,Heidrick, Zachary,Khosropour, Ahmad R.,Beyzavi, M. Hassan
, p. 37835 - 37840 (2018)
The combination of continuous flow technology with immobilizing of only 0.13?mol% of triflic acid (TfOH) on silica-encapsulated superparamagnetic iron oxide nanoparticles (SPIONs) under solvent-free conditions successfully provided a powerful, efficient, and eco-friendly route for the synthesis of plasticizers. The turnover frequency value in micro-flow conditions varied in the range of 948.7 to 7384.6 h?1 compared to 403.8 to 3099 h?1 for in-flask. This technique works efficiently, encouraging future applications of micro-flow nano-catalysis in green chemistry.
Lubricant base oil and ester compounds
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Paragraph 0079; 0099; 0100, (2019/06/29)
[Problem] To provide: an ester compound having low viscosity, excellent fluidity even at low temperatures, and a high viscosity index; and a lubricating oil base oil that blends said compound therein. [Solution] The present invention provides an ester compound indicated by formula (I). Formula (I) (in formula (I), R1 indicates a C1–35 hydrocarbon group and at least one hydrogen in the hydrocarbon group can be independently substituted for a group indicated by formula (II)). Formula (II) (in formula (II), R2 indicates a C1–30 linear alkyl or a C3–30 branched alkyl.)
