103002-82-0

Upstream product

• 103002-80-8 Toluene-4-sulfonic acid (4E,8Z)-(3R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-10-cyano-10-(1-ethoxy-ethoxy)-3-isopropyl-deca-4,8-dienyl ester 
• 112538-42-8 Toluene-4-sulfonic acid (E)-(3R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-10-hydroxy-3-isopropyl-dec-4-en-8-ynyl ester 
• 103002-77-3 Toluene-4-sulfonic acid (4E,8Z)-(3R,6R)-6-(tert-butyl-diphenyl-silanyloxymethyl)-10-hydroxy-3-isopropyl-deca-4,8-dienyl ester 

Downstream Products

• 61228-92-0 (+/-)-periplanone 
• 103002-86-4 (E)-(1R,5S,8S,10R)-8-(tert-Butyl-diphenyl-silanyloxymethyl)-5-isopropyl-11-oxa-bicyclo[8.1.0]undec-6-en-2-one 

Relevant academic research and scientific papers

Stereocontrolled Synthesis of American Cockroach Sex Pheromone, Periplanone B

The stereoselective synthesis of periplanone B, the sex excitant pheromone of the American cockroach, and a discussion of the diastereoselectivity of C(2), C(3)-epoxidation based on MM2 calculations are presented.