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[Rh(CO)2(1,3-bis(diphenylphosphino)propane)]OTf is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1030632-16-6 Structure
  • Basic information

    1. Product Name: [Rh(CO)2(1,3-bis(diphenylphosphino)propane)]OTf
    2. Synonyms:
    3. CAS NO:1030632-16-6
    4. Molecular Formula:
    5. Molecular Weight: 720.448
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1030632-16-6.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [Rh(CO)2(1,3-bis(diphenylphosphino)propane)]OTf(CAS DataBase Reference)
    10. NIST Chemistry Reference: [Rh(CO)2(1,3-bis(diphenylphosphino)propane)]OTf(1030632-16-6)
    11. EPA Substance Registry System: [Rh(CO)2(1,3-bis(diphenylphosphino)propane)]OTf(1030632-16-6)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1030632-16-6(Hazardous Substances Data)

1030632-16-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1030632-16-6 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,3,0,6,3 and 2 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1030632-16:
(9*1)+(8*0)+(7*3)+(6*0)+(5*6)+(4*3)+(3*2)+(2*1)+(1*6)=86
86 % 10 = 6
So 1030632-16-6 is a valid CAS Registry Number.

1030632-16-6Downstream Products

1030632-16-6Relevant articles and documents

Benzene hydrogenation by silica-supported catalysts made of palladium nanoparticles and electrostatically immobilized rhodium single sites

Barbaro, Pierluigi,Bianchini, Claudio,Dal Santo, Vladimiro,Meli, Andrea,Moneti, Simonetta,Pirovano, Claudio,Psaro, Rinaldo,Sordelli, Laura,Vizza, Francesco

, p. 2809 - 2824 (2009/02/03)

The complex [Rh(cod)(dppp)]OTf (Rh(cod)) has been immobilized onto silica-supported palladium nanoparticles (Pd/SiO2) via a dual H-bond/ionic interaction (dppp = 1,3-bis(diphenylphosphino)propane; cod = cycloocta-1,5-diene). The product obtained, Rh(cod)-Pd/SiO2, has been employed to catalyze the hydrogenation of benzene to cyclohexane, showing much higher activity as compared to Pd/SiO2, while Rh(cod) grafted on bare silica (Rh(cod)/SiO2) is totally inactive. The catalyst generated by Rh(cod)-Pd/ SiO2 exhibits a remarkable stability and can be recycled several times with no loss of activity, even if exposed to air. In situ and ex situ EXAFS and DRIFTS measurements, batch catalytic reactions under different conditions, deuterium labeling experiments, and model organometallic studies, taken altogether, have provided valuable mechanistic information. The reduction of benzene to cyclohexa-1,3-diene occurs with the cooperation of the two metals, while the rhodium single sites are more effective than the palladium nanoparticles in the hydrogenation of cyclohexa-1,3-diene to cyclohexane.

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