1030835-95-0

Upstream product

• 1031354-04-7 { (4S,5S)-5-[(R)-2-(tert-butyldimethylsilyloxy)propyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 866531-31-9 (2R)-1-(oxiran-2-yl)propan-2-ol 
• 866043-88-1 tert-butyldimethyl(((2R)-1-(oxiran-2-yl)propan-2-yl)oxy)silane 
• 1030835-70-1 (3S,5R)-5-((tert-butyldimethylsilyl)oxy)-hex-1-en-3-ol 
• 1334848-86-0 (1S,3R)-3-(tert-butyldimethylsilyloxy)-1-((S)-oxiran-2-yl)butan-1-ol 
• 1334848-89-3 (3S,4S,6R)-6-(tert-butyldimethylsilyloxy)hept-1-ene-3,4-diol 
• 1334848-90-6 tert-butyl-(((R)-1-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)-propan-2-yl)oxy)dimethylsilane 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 1233961-23-3 ((4S,5S)-5-((R)-2-hydroxypropyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl 4-methylbenzenesulfonate 

Relevant academic research and scientific papers

Stereoselective synthesis of ophiocerins A and C

An efficient synthesis of ophiocerins A and C has been achieved via a common intermediate. The stereogenic centers were generated by means of Jacobsen's hydrolytic kinetic resolution and Sharpless kinetic resolution.

Substrate-controlled stereoselective synthesis of ophiocerin C

A novel stereoselective total synthesis of ophiocerin C was accomplished starting from l-(+)-tartaric acid. The C3,C4 vic-diol moiety was obtained from tartaric acid, and the stereogenic centre at C6 was created by substrate-controlled epoxidation and subsequent regioselective cleavage of the epoxide ring. Georg Thieme Verlag Stuttgart.