1031-47-6

Basic information

• Product Name: TRIAMIPHOS
• Synonyms: 5-amino-1-(bis(dimethylamino)phosphinyl)-3-phenyl-1,2,4-triazole;5-amino-1-bis(dimethylamide)phosphoryl-3-phenyl-1,2,4-triazole;5-amino-1-bis(dimethylamido)phosphoryl-3-phenyl-1,2,4-triazole;5-amino-3-fenil-1-bis(-dimetilamino)-fosforil-1,2,4-triazolo;5-amino-3-fenil-1-bis(-dimetilamino)-fosforil-1,2,4-triazolo[qr];5-amino-3-fenyl-1-bis(dimethyl-amino)-fosforyl-1,2,4-triazool;5-amino-3-fenyl-1-bis(dimethyl-amino)-fosforyl-1,2,4-triazool[qr];5-amino-3-phenyl-1,2,4-triazole-1-yl-n,n,n’,n’-tetramethylphosphodiamide
• CAS NO: 1031-47-6
• Molecular Formula: C12H19N6OP
• Molecular Weight: 294.29
• Mol File: 1031-47-6.mol
• Article Data: 9

Chemical Properties

• Melting Point: 167.5°C
• Boiling Point: 471.7°Cat760mmHg
• Flash Point: 2 °C
• Appearance: /solid
• Density: 1.32g/cm³
• Vapor Pressure: 4.53E-09mmHg at 25°C
• Refractive Index: 1.637
• Storage Temp.: APPROX 4°C
• PKA: 1.67±0.50(Predicted)
• Water Solubility: 0.25g/L(20 oC)
• CAS DataBase Reference: TRIAMIPHOS(CAS DataBase Reference)
• NIST Chemistry Reference: TRIAMIPHOS(1031-47-6)
• EPA Substance Registry System: TRIAMIPHOS(1031-47-6)

Safety Data

• Hazard Codes: T+,Xn,F
• Statements: 27/28-36-20/21/22-11
• Safety Statements: 22-28-36/37-45-36-26-16
• RIDADR: 2783
• HazardClass: 6.1(a)
• PackingGroup: II
• Hazardous Substances Data: 1031-47-6(Hazardous Substances Data)

Usage

Description

TRIAMIPHOS, also known as Triadimefon, is a systemic fungicide belonging to the class of triazoles. It is a white to off-white crystalline solid with a chemical formula of C16H17Cl2N3. TRIAMIPHOS is effective in controlling powdery mildew on various crops, including apples and ornamentals. However, it has been discontinued by the U.S. supplier.

Uses

Used in Agriculture:
TRIAMIPHOS is used as a fungicide for the control of powdery mildew in apple and ornamental crops. It helps protect plants from fungal infections, ensuring a healthy growth and higher yield.
Please note that the provided materials only mention the use of TRIAMIPHOS in agriculture, specifically for controlling powdery mildew on apples and ornamentals. There might be other applications, but they are not mentioned in the given materials.

Reactivity Profile

Organophosphates, such as TRIAMIPHOS, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Health Hazard

TRIAMIPHOS is an organic phosphorus insecticide. Organic phosphorus insecticides are absorbed by the skin, as well as by the respiratory and gastrointestinal tracts. It is a cholinesterase inhibitor.

Fire Hazard

As for other organophosphorus pesticides, containers may explode in heat of fire. Heat may cause decomposition and evolution of highly toxic fumes of nitrogen oxides and phosphorus oxides.

Safety Profile

Poison by ingestion, skin contact, intraperitoneal, and possibly other routes. An experimental teratogen. Mutation data reported. When heated to decomposition it emits very toxic fumes of PO, and NOx,.

InChI:InChI=1/C12H19N6OP/c1-16(2)20(19,17(3)4)18-12(13)14-11(15-18)10-8-6-5-7-9-10/h5-9H,1-4H3,(H2,13,14,15)

Relevant articles and documents

Six-membered heterocyclic derivatives of N'-substituted N,N'-diacylhydrazines

This invention relates to insecticidal compositions containing six-membered heterocyclic derivatives of N'-substituted-N,N'-diacylhydrazines, methods of using such compositions and novel six-membered heterocyclic derivatives of N'-substituted-N,N'-diacylhydrazines.

1-Dimethylcarbamoyl-3-substituted-5-substituted-1H-1,2,4-triazoles

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Six-membered heterocyclic derivatives of N'substituted-N,N'-diacylhydrazines

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