10311-36-1

Upstream product

• 73323-87-2 4'-Bromo-2',6'-dichloro-3'-aminoacetanilide 
• 13953-09-8 4-bromo-2,6-dichloroacetanilide 
• 13953-10-1 4'-Bromo-2',6'-dichloro-3'-nitroacetanilide 
• 50917-27-6 3-acetamido-2,4-dichlorobenzoic acid 
• 10311-35-0 N-(2,6-dichloro-3-nitrophenyl)acetamide 

Downstream Products

• 73323-88-3 3-Acetamido-2,4-dichlorobenzenesulfonyl chloride 
• 13055-37-3 3-Amino-2,4-dichloro-N¹,N¹-dimethylbenzenesulfonamide 
• 73323-89-4 3-Acetamido-2,4-dichloro-N,N-dimethylbenzenesulfonamide 
• 10311-56-5 N-<2,6-Dichloro-3-(dimethylsulfamoyl)phenyl>anthranilic acid 

Relevant academic research and scientific papers

MOLECULES HAVEING PESTICIDAL UTILIY AND INTERMEDIATES, COMPOSITIONS AND PROCESSES RELATED THERETO

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

Preparation of Ortho-Substituted Benzoic Acids by the Copper(II)-Catalyzed Reaction of Diphenyliodonium-2-carboxylate with Anilines and Other Nucleophiles

Diphenyliodonium-2-carboxylate (DPIC) reacts readily in copper ion catalyzed condensations with a variety of nucleophiles to give ortho-substituted benzoic acids.These reactions occur at temperatures (80-100 deg C) below those at which benzyne formation and other side reactions become important.The nature of the Cu(II) catalysis appears to be different from the more common Cu(I) catalysis of diaryliodonium reactions in that high specificity in the displacement reaction is retained.Products obtained directly from DPIC condensations include N-anthranilic acid (5b), N-methyl-N-phenylanthranilic acid (5c), N-mesyl-N-(2,3-dimethylphenyl)anthranilic acid (5d), N-(3-chloro-2-methylphenyl)-N-tosylanthranilic acid (5e), and o-(2,3-dimethylphenoxy)benzoic acid (5f).Compound 5d has been cyclized to N-(2,3-dimethylphenyl)-1H-2,1-benzothiazin-4(3H)-one 2,2-dioxide (6).