103130-64-9

Upstream product

• 492-37-5 hydratropic acid 
• 25145-43-1 2-phenylpropionyl chloride 
• 34713-70-7 2-Phenylpropanal 
• 112-29-8 1-bromo dodecane 
• 20157-33-9 n-decylmagnesium chloride 
• 155222-99-4 1-(4-morpholinyl)-2-phenyl-1-propanone 

Relevant academic research and scientific papers

Addition of organocerium reagents to morpholine amides: synthesis of important pheromone components of Achaea janata.

Readily preparable morpholine amides hitch in good yields with organocerium reagents to produce ketones. Even in the presence of substrates and reagents with high steric hindrance, the organometallic compounds prepared from dry cerium(III) chloride and organomagnesium or organolithium compounds at -78 degrees C add cleanly to morpholine amides. The low cost of starting materials makes this new scheme of synthesis very interesting for the preparation of biologically important pheromones.

Stereoselective Oxidation of β-Methyl-sec-alcohols and α-Methylketones by Corynebacterium equi IFO 3730

The enzyme system of Corynebacterium equi IFO 3730 catalyzed the diastereo-selective oxidation of β-methyl-sec-alcohols.For example, only the erythro isomer of 5-methyl-6-tetradecanol was oxidized to the corresponding ketone, the threo-alcohol remaining.M