1031379-05-1Relevant articles and documents
Palladium-pincer complex catalyzed C-C coupling of allyl nitriles with tosyl imines via regioselective allylic C-H Bond Functionalization
Aydin, Juhanes,Szabo, Kalman J.
supporting information; experimental part, p. 2881 - 2884 (2009/05/27)
(Chemical Equation Presented) A mechanistically new palladium-pincer complex catalyzed allylation of sulfonimines is presented. This reaction involves C-H bond functionalization of allyl nitriles under mild conditions. The reaction proceeds with a high regioselectivity, without allyl rearrangement of the product. Modeling studies indicate that the carbon-carbon bond formation process proceeds via (η1-allyl)palladium pincer complex intermediates.